Metallo-Supramolecular Polymers:Synthesis, Properties, and Device Applications(NIMS Monographs)

金属超分子聚合物:合成、特性与设备应用

化学史

原   价:
552.5
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442.00
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发货周期:预计8-10周发货
作      者
出  版 社
出版时间
2019年11月20日
装      帧
平装
ISBN
9784431568896
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页      码
89
语      种
英文
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图书简介
This book introduces the synthesis, electrochemical and photochemical properties, and device applications of metallo-supramolecular polymers, new kinds of polymers synthesized by the complexation of metal ions and organic ditopic ligands. Their electrochemical and photochemical properties are also interesting and much different from conventional organic polymers. The properties come from the electronic intra-chain interaction between the metal ions and the ligands in the polymer chain. In this book, for example, the electrochromism that the Fe(II)-based metallo-supramolecular polymer exhibits is described: the blue color of the polymer film disappears by the electrochemical oxidation of Fe(II) ions to Fe(III) and the colorless film becomes blue again by the electrochemical reduction of Fe(III) to Fe(II). The electrochromism is explained by the disappearance/appearance of the metal-to-ligand charge transfer absorption. The electrochromic properties are applicable to display devices such as electronic paper and smart windows.
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