图书简介
Reversible deactivation radical polymerization has made significant progress within the last two decades. New systems have been discovered, substantial progress has been achieved in understanding the mechanism and kinetics of reactions involved in all reversible deactivation radical polymerization systems. Significant progress has also been made towards developing a comprehensive relationship between molecular structure and macroscopic properties. Several commercial applications of reversible deactivation radical polymerization have been announced and it is anticipated that new products made by controlled/living radical polymerization will soon be on the market.
Preface ........................................................................................................................ ...... ix; 1. Polyhomologation and ATRP: A Perfect Partnership toward Unique; Polyethylene-Based Architectures .......................................................................... 1; De Wang, Zhen Zhang, Hefeng Zhang, Yves Gnanou, and Nikos Hadjichristidis; 2. Autocorrelation in Multiblock Copolymers ........................................................ 25; Simon Harrisson; 3. Aqueous Visible-Light RAFT Polymerizations and Applications ..................... 43; C. Adrian Figg and Brent S. Sumerlin; 4. On the Use of Redox Initiation in Aqueous RAFT Polymerisation ................... 57; Liam Martin, Guillaume Gody, and Sebastien Perrier; 5. Synthesis of Well-Defined Polystyrene with Molar Mass Exceeding 500; kg/mol by RAFT Emulsion Polymerization ........................................................ 81; Jinwei Fang, Kun Yan, and Yingwu Luo; 6. Multidentate Block Copolymer Stabilization: A Versatile Strategy for; Colloidal Superparamagnetic Iron Oxide Nanoparticles Exhibiting; Excellent Colloidal Stability and Enhanced Positive MRI Visualization ....... 107; Nicky Chan, Puzhen Li, Wangchuan Xiao, Depannita Biswas, Philippe Legros,; Marc-Andre Fortin, and Jung Kwon Oh; 7. Synthesis of a Structurally Controlled Polyacrylonitrile Gel for; Energy-Storage Devices by an Organotellerium-Mediated Radical; Copolymerization and Subsequent Cross-Linking Reaction ........................... 129; Wenjuan Li, Masatoshi Tosaka, and Shigeru Yamago; 8. Programmed Self-Assembly of Amphiphilic Random Copolymers in Water; via Controlled Radical Polymerization .............................................................. 143; Takaya Terashima; 9. Direct Hydrophilic Modification of Polymer Surfaces via Surface-Initiated; ATRP ..................................................................................................................... 157; Yuji Higaki, Motoyasu Kobayashi, and Atsushi Takahara; 10. Macromolecular Templates for Synthesis of Inorganic Nanoparticles ........... 169; Joanna Pietrasik, Katarzyna Budza?ek, Yaoming Zhang, Krzysztof Ha?agan, and; Marcin Kozanecki; 11. Drug-Initiated Synthesis of Cladribine-Based Polymer Prodrug; Nanoparticles: Biological Evaluation and Structure Activity; Relationships ........................................................................................................ 201; Yinyin Bao, Elise Guegain, and Julien Nicolas; 12. Biocatalytic Polymerization, Bioinspired Surfactants, and Bioconjugates; Using RAFT Polymerization ............................................................................... 219; Alex P. Daniselson, Melissa Lucius Dougherty, Rebecca Falatach,; Thaiesha A. Wright, Emily E. Clark, Andrew Craig, Indra D. Sahu,; Jason A. Berberich, Richard C. Page, Gary A. Lorigan, and Dominik Konkolewicz; 13. Biomimetic Anchors for Antifouling and Antibacterial Polymeric; Coatings ................................................................................................................ 233; Li Qun Xu, Koon-Gee Neoh, and En-Tang Kang; 14. Recent Progress on Grafting-onto Synthesis of Molecular Brushes by; Reversible Deactivation Radical Polymerization and CuAAC Coupling; Reaction ................................................................................................................. 263; Weiping Gan, Xiaosong Cao, and Haifeng Gao; 15. In Situ Terminal Functionalization of Polystyrene Obtained by Quasiliving; ATRP and Subsequent Derivatizations .............................................................. 281; Gyorgy Kasza, Gyorgyi Szarka, Andrea Bodor, Gergely Kali, and Bela Ivan; Editors’ Biographies .................................................................................................... 297; Indexes; Author Index ................................................................................................................ 301; Subject Index ................................................................................................................ 303
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