Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene(Springer Theses)

物理化学

原   价:
1598.75
售   价:
1279.00
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平台大促 低至8折优惠
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出  版 社
出版时间
2018年07月07日
装      帧
平装
ISBN
9789811092473
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页      码
141
语      种
英文
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图书简介
This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd–Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.<
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