图书简介
Environmental Inorganic Geochemistry discusses the structure, bonding and reactivity of molecules and solids of environmental interest, bringing the reactivity of nonmetals and metals to environmental chemists from diverse fields. Throughout the book, fundamental chemical principles are illustrated with relevant environmental examples and applications. Emphasis is placed on applications involving inorganic, bioinorganic and organometallic compounds of environmental interest; electron transfer processes in the environment; and the activation of small molecules to form organic compounds necessary for life. Thermal and photochemical reactions are presented, the principles of quantum mechanics for atoms and molecules are reviewed, and the periodicity of the elements is discussed in this context. The discussion emphasizes the conceptual frontier molecular orbital theory approach and does not go into rigorous mathematical development. HYPERCHEM, a molecular modeling package from HYPERCUBE, is used to describe molecular properties, sketch the shape of orbitals and compare energy of orbitals with experimental data. A substantial list of the HOMO and LUMO energies for diatomic and polyatomic compounds is also provided to help the reader understand reactivity. Topics covered include: Introduction to environmental inorganic geochemistry Thermodynamics of redox reactions Inorganic chemistry review Covalent bonding review Band theory Transition metal reaction mechanisms Transition metals in natural systems ( Iron and manganese in the environment Metal uptake by organisms Supplementary material including PowerPoint slides and further examples are provided online. Environmental Inorganic Geochemistry is a rapid assimilation textbook for those studying and working in areas of environmental chemistry.
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